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A25375 Chymical disceptations, or, Discourses upon acid and alkali wherein are examined the object of Mr. Boyle against these principles : together with a reply to a letter of Mr. S. Doctor of Physick & fellow of the colleg of *** : wherein many errors are corrected, touching the nature of these two salts / by Fran. Andre, Dr. in Physick ..., faithfully rendered out of French into English by J.W. ; to which is added, by the translator, a discourse of phlebotomy shewing the absolute evils, together with the accidental benefits thereof, in some cases.; Entretiéns sur l'acide et sur l'alkali. English Saint André, François de, fl. 1677-1725. 1689 (1689) Wing A3113A; ESTC R30709 47,738 222

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The Acid Salt is easily known by the Tast and Smell and by the Firmentation which it makes with Alkali's as Spirit of Sulphur This Salt is composed of small sharp pointed parts which insinuate themselves into the Pores of those Bodies they meet with and make either a Dis-union of their Parts or a Coagulation for according to the different Motions particular Figure Subtilty or Grosness of these Points and the disposition of those Bodies they either pass through them with Violence and scatter their parts one from another or else they are Entangled therein in such sort that they lose their Force and their Motion in them Remaining very often sticking to them We observe in effect That Acid Salts dissolve hard Bodies as Stones and Metals except Gold which cannot be dissolv'd but in salt Menstruums and coagulates the most part of soft and fluid Bodies such as Milk Blood. c. PYR. Then there are Acid Salts of different Natures EUB. There are as many different sorts of Acid salts as there are different Bodies in Nature and though the Particles or Attoms which compose them are all sharp yet that hinders not but they have nevertheless all different Figures which causes all the compound Mineral Salts in which the Acid salt predominates as Niter Vitriol c. and also the Essential Salts of Plants to take all different Figures in their Coagulations according to the Nature of the Acid which determines them whence some are formed Pyramidical as Niter others winding like a Screw as Vitriol c. PYR. Whence comes it That Acids dissolve Silver and other Metals and do not dissolve Gold and on the contrary salt Liquors dissolve Gold and touch neither Silver nor other Metals EUB. Gold being almost all Sulphur cannot be corroded by Acids of what nature soever they be it must be salt Liquor and as perfect a Spirit of Salt as can dissolve which in Corrosion must re-take the Nature of Salt Silver and other Metals having on the contrary more Mercury than Sulphur can never be dissolved in salt Menstruums for there is none but Acid Spirits that can dissolve them To confirm both to you You ought to take Notice That those that work in Slat Petar after they have extracted it draw forth yet a Salt a great deal less acid which is of the Nature of common salt which they call Sal centrique which when it is Resolved into a Liquor dissolves Gold after the same Manner as Spirit of Salt doth and in corroding re-takes the Nature of Salt and dissolves neither Silver nor other Metals PYR. Suppose that Gold be almost all Sulphur and then it is easy to comprehend Why it cannot be dissolved by Acids but only by salt Menstruums EUB. Have you never observed That when Gold is in flux if the end of an iron Rod be put therein it will be calcined and reduced into Scoria after the same manner as if it had been burnt with common Sulphur and that Argent vive forsakes all Metals to join it self with Gold which it renders as brittle as Glass How should Gold calcine Iron and be in such wise penetrated by Mercury as to become brittle as Glass if it did not abound with Sulphur first you know That Iron can't be calcin'd but by Sulphur which seeing Gold calcines consequently Gold must be a Sulphur Secondly Mercury being a powerful Metallick Alkali though imprisoned which is not joined but with a Sulphur of its own Nature would not quit other Metals to be joined to Gold if Gold had not more Sulphur than others and the Mercury renders it not otherwise brittle but because it absorbs its Sulphur and dis-unites the parts thereof PYR. Mercury nevertheless does not destroy the Body of Gold which it would do if it absorbed the Sulphur and disunited the parts thereof EUB. That is not a Consequence That because the Mercury absorbed the Sulphur of Gold and scattered the parts thereof It must therefore destroy it for the Sulphur of Gold being most fixed and the Mercury on the contrary being most volatile there cannot be made an exact Union betwixt them two that is to say by small parts and the Mercury being cast into the fire quits in that moment the Sulphur of the Gold which it had absorbed and flies away and the Sulphur of the Gold is re-united to its own Mercury and the Gold becomes as hard as fixed and as solid as it was before Moreover how should Gold become fulminant if it did not abound in Sulphur The composition of Aurum fulminans makes us sufficiently sensible of it They cause Gold to dissolve in Aqua Regis which they afterwards precipitate by little and little with Oil of Tartar made per Deliquium there is then made a Union of the Alkali of Tartar with the Acid spirit of the Nitar which composed the Aqua for t and there is produced therefrom a new-made Nitar this Nitar being united to the Sulphur of the Gold is inflamed and produceth all those surprizing Effects which we take Notice of therein PYR. The Nitar would Produce these Effects alone or being mingled with the Sal Armoniack or common Salt which was put into the Aqua Regia EUB. Salt-Petar is never inflamed but when it is mingled with some Sulphur as with common Sulphur in Gun-pouder and Pulvis fulminans or with the Sulphur of Antimony when one makes Regulus and Liver c. Common salt and Sal Armoniack are so far from rend'ring Salt-Petar inflamable that they extinguish fire with more force than common Water doth it therefore follows That the Sulphur of the Gold is united with the Salt-Petar and causes this Deflagration PYR. We see never●●●less That Salt-Petar is inflamed at the same time that one puts it on burning Coals EUB. The Salt Petar is not inflamed then but because it is united to the Sulphur of the Coals for if one put some Salt-Petar into a Crucible and make the Crucible red-hot it simply melts and is not inflamed but when one casts some Sulphur or some Coal thereinto And to convince you fully That Gold contains a great deal more Sulphur than other Metals You may take Notice That one cannot make either Silver Lead or Tin fulminant because These Metals have only a very little Sulphur which is wholy absorbed by their Mercury There is nothing in the world which ows not its Birth to Acid Salt nothing can live nor be multiplied without it It is that Soul of the World of which the Antients have so often told us Spiritus intus alit totamque infusa per artus Mens agitat Molem The Spirit within and the Mind infused through the Members nourisheth and agitates the whole Body In a word The Acid Salt is the Author of the Construction of every Body and the absolute Master of Alkali Salts it prints them as a Seal is made on Wax with all sorts of Characters and makes thereof several different Bodies according to the diversity of its
Salts namely an Acid Salt and an Alkali That there are Three sorts of Spirits or Mercuries an Acid spirit a sharp biting spirit and a burning spirit that the Acid spirit was an Acid Salt dissolv'd in a little flegm the sharp spirit a volatile Alkali dissolved also in a little flegm and the burning spirit a Sulphur and Sulphur an inveloped Acid I have now no more to do but to bring you some Experiments to convince you of this Truth I. EXPERIMENT Which proves that Acià Spirits are no other than Acid Salis dissolved in some flegm An Acid Spirit ferments it self with all Alkali's and makes thereof Salts of the same nature with those from which it was drawn as the Spirit of Niter c. II. EXPERIMENT A sharp Spirit is a Volatile Alkali dissolved in some Flegm All sharp spirits ferment themselves with Acids and precipitates Vitriol of Mars dissolved in water as the volatile spirit of sal-Armoniack c. III. EXPERIMENT Which proves that burning spirits are Sulphurs Plants give a great deal of Oil and a little spirit before they are fermented and they give on the contrary a great deal of spirit and a very little Oil after they are fermented because the parts thereof unloose themselves and dis-intangle themselves one from the other in the time of Fermentation and remain bound and intangled one in the other before the Fermentation was made which clearly shews that a burning spirit is a vegetable sulphur but much less intangled than the other sulphurs of Vegetables IV. EXPERIMENT Which proves the same Experience shews us That burning spirits exposed to the air for some time are changed into Oils of the same nature as those of the Plants from which they were drawn V. EXPERIMENT Which demonstrates that burning Spirits are envelloped Acids There is drawn from salt of Saturn a burning spirit of the same nature as spirit of Wine this spirit cannot come but from the Acid of the distilled Vinegar which entred into the Composition of the salt of Saturn whose parts are bound and intangled one in the other VI. EXPERIMENT Which proves that Oyles of Vegetables are envelloped Acids Oyl corrodes Copper and turns it into Verdigrise there are none but Acids which can produce this Effect and therefore consequently Oil ought to be Acid. VII EXPERIMENT Which proves the same Fire is an Oyl whose parts are unwrapped and in a most Violent Agitation and Motion fire is Acid since it renders Corals Salt Oyl which is the matter thereof ought then to be Acid. VIII EXPERIMENT Which proves the same Soap does furnish us still with a most convincing Proof That Oils of Vegetables are enveloped Acids Soap is made with three parts of Alkali and two of Oil which two matters are mingled together and then boiled and there comes therefrom a salt body which is Soap you know that saltness comes from the mixture of Acid with Alkali and that consequently seing soap is salt the Soap ought not only to have Alkali in it but also Acid the Acid cannot be communicated to it but by the Oil which was put thereto which Acid unwraps it self in the Alkali which was joined thereto it must be therefore that Oil is an envelloped Acid. PYR. It may be also Tha● the Fire communicated this saltness to the soap as it did to the Corals for you have already told me That when one reverberates them in a violent fire for some daies and nights they become intirely Salt and ferment no more with Acids EUB. The same thing cannot be said of soap as of Corals because one must reverberate the Coral six daies and nights to render them salt and the saltness of Soap is communicated to it in a short time even as soon as the Acid of the Oil is dis-enveloped and absrobed by the Alkali which was put thereto likewise the soap augments not in weight on the fire as the Corals do they augmenting a fifth part IX EXPERIMENT Which proves that the Fat 's and Suets of Animals are envelloped Acids Soap is made with the suet of Animals after the same manner as it is with the Oils of Vegetables It must be therefore that the Fat 's and Suets of Animals may be envelloped Acids as the Oils of Vegetables are X. EXPERIMENT Which proves the same The flame of Fat 's and Suets is Acid it destroies Iron and reduces it into Scoria's c. Grease's and Suets ought then to be Acids XI EXPERIMENT Which proves that the Sulphurs of Minerals and Metals are envelloped Acids Sulphur of Antimony elevates Mercury into Cinnabar as we observed in the Composition of its Butter How should the Sulphur of Antimony elevate Mercury which is an Alkali into Cinnabar if it were not Acid It follows therefore that the Sulphur of Antimony is acid Common Sulphur elevates Mercury into Cinnaber and it may be made use of for the position of Soap as well as the Oils of Vegetables and Fat 's of Animals In a word the Sulphur of Gold is acid since it produceth the same Effects as Acids do for it calcines Iron which cannot be calcin'd but by Acids c. The Sulphurs of Minerals and Metals are then envelloped Acids PYR. In Truth These Principles are most sensible and palpable EUB. This is not yet enough to have discovered thus much to you concerning Acid Salt Alkali Salt in particular but 't is needful that I press the thing more home and that I make you know what these II Salts are capable to do when they are once united These two Salts are in regard one of the other as the Soul is in regard of the Body and the Body in respect of the Soul The the Acid Salt is the Soul which animates and vivifies the Body and the Alkali Salt is the Body which receiveth the Soul and unites it self so intimately therewith that this Soul can be nothing without this Body nor this Body without this Soul. When they are once intimately united as we observe in common Salt it is impossible to separate them one from the other and though these two Salts seem at first sight to have an Antipathy one against the other by the Fermentation which they make when they meet Nevertheless they embrace and unite in such wise together that very far from destroying themselves they are coagulated and make no more but one and the same Body And it may be said thereof as the Incomparable Hypocrates hath said in his Book of DIET speaking of Fire and Water that though these two Elements differ in Quality nevertheless they agree in use That they are sufficient for all Bodies and for themselves but neither the one nor the other separated can be sufficient neither for any other body nor for it self Constituuntur saith he tum Animantia tum alia omnia tum homo ipse ex duobus differentibus quidem facultate Concordibus vero commodis usu haec ambo simul sufficientia sunt tum aliis omnibus tum mutuo
the Regeneration of compound Mineral Salts and the Essential Salts of Plants for it is most certain That Acids are not the destroyers of Bodyes nor Alkali's their Authors since all Alkali's are determined by Acids to make Bodyes of the same Nature with those from which they were drawn and if it happens sometimes That Acids destroy some Bodies as common Sulphur doth Iron that happens because there is little Alkali to be found in those Bodyes and the Acid being intangled therein in a great deal of Earth it may easily be disintangled therefrom by another Acid the which intirely destroys the Composition but that happens not in those Bodyes where the Acid is fixed and united intimately with its Alkali as it is in Gold Silver c. You bring us Tartar of Wine for the first of all Acids and you prove it after so convincing a manner ●●g 93. That the same Reasoning may be applyed in all its force to all the other Tartars of Vegetables It is the first say you in its generation and Action it is the first in its generation because it is produc'd such by nature for it is in Grapes together with the Alkali of wine and so long as Nature governs them they have not any motion of alteration one against the other c. but as soon as Nature doth cease to govern them they ferment themselves one with the other into Wine c. May not the same thing be said of all the other Vegetables They have all their Acid and Alkali produced such by Nature they are not dis-united but when Nature ceases to govern them they are fermented in their Juices as the Alkali and Acid of Grapes are in Wine You are not contented to assure us That Tartar is the first of Acids but also That its Acid consists in its Salt and That that which is distilled therefrom is the Volatile Alkali of Wine which this Acid had absorbed The Anatomy of Tartar will perhaps make you be of another Opinion for there is drawn therefrom first a Flegm by Distillation Secondly an Acid Spirit which ferments with all Alkali's Thirdly a stinking Oil and lastly a fixed Salt which is separated from its Caput Mort. by Lixiviation which ferments with all Acids and precipitates Vitriol of Mars dissolved in Water The Acid spirit of Tartar is of the same Nature with that of Vinegar as may be seen by this Experiment ℞ some Salt of Tartar and pour thereupon good Vinegar until it will take in no more and there will be made a regenerated Tartar like to that of Wine whose sourness is gone You may perceive then by this That that Spirit which is drawn from Tartar is not the volatile Alkali of Wine which the Tartar had absorbed as you teach us but it is on the contrary the volatile Acid of Wine which causeth it in time to degenerate into Vinegar The black and stinking Oil which went forth after the Flegm and Spirit is an enveloped Acid as are all the Oils of Vegetables In a word The Salt that is drawn from Tartar is as powerful an Alkali as any there is in Nature which as I said even now ferments with all Acids ' and does precipitate Vitriol of Mars dissolved in Water It seems also you have acknowledged this Truth when you said That Oil of Tartar made per deliquium which is no other thing but fixed Salt of Tartar dissolved in some Flegm did ferment with the Spirits of Salt Vitriol Pag. 97. Sulphur and Niter and did precipitate after the Fermentation some Matter from those Bodies Oil of Tartar is therefore an Alkali since it ferments with Acid Spirits for as you grant there is none but Alkali's which can ferment with Acids and it is false that you assure us That this Oil is Acid for if it was Acid it would ferment with Alkali's and never with Acids the which is contrary to what we see Pag. 98 99 100. The Reason which you render of the Effervescence which happens in the Dissolution of Metals in Aqua fort is a Subject as little satisfactory for you say That it is not the Aqua fort that causes this Dissolution and Effervescence but rather a volatile sulphurous Spirit which animates the Aqua Fort. to the Dissolution of the Mettal since that being evaporated or separated therefrom by the Acid of Salt of Tartar the rest of the Water acts no more for assuredly continue you it is this imperfect or to speak more properly embrionated Sulphur which symbolizeth with the Sulphur of a Mettal and more or less with one than with another whence come the Diversity of Aqua fortis and that one acts upon one Mettal and not upon another c. This Sulphur is impatient for a union with a Sulphur more perfect than it self therefore it searches through the Mercury and striving to be united with it per minima it divides it c. Experience fully destroyes the appearances of this Reasoning for it is most certain That Acids as Spirit of Niter dissolves imperfect Metals which have more Mercury than Sulphur as Silver Lead c. and as for Gold which hath a great deal more Sulphur than Mercury it cannot be dissolv'd but in salt Menstruums as Spirit of Sea-salt I have explained all these different Effects so clearly in the preceeding Discourses of this Book That the repetition thereof would be both useless and troublesom And as to the Hindrance that Oil of Tartar brings to those Dissolutions which you attribute to its Acidity it is not at all probable since I have formerly shewn That it was an Alkali and the true Reason of it is That the Oil of Tartar being a powerful Alkali absorbs the Acids which held the Metals in Dissolution and the Metals being no longer agitated or stir'd by their points are precipitated into a powder to the bottom of the Vessel Truly I see as little Justice in your Definition of Alkali You argue it to be a thing made Salt by Cremation Pag. 102. as though it was not a Salt before and this Definition doth in no wise explain the Nature of Alkali but only agrees with fixed Alkali yet it is certain that some are Volatile which are elevated sublimed with the least Heat as your self acknowledgeth p● 94.95 where you speak of Tartar You say It retains the volatile Alkali of Wine which causeth it to break the Vessels by its combating with the Acidity of the Tartar when it is distilled alone by Retort The Recipient being very exactly luted the fire too much prest But I have moreover sufficiently formerly proved That Alkali as well as Acid was actually in all Bodies and that to be Alkali it is not necessary that a Body be made salt by Cremation Moreover the Doctrine which you promote contradicts it self Pag 104 105. for if the Alkali was no other as you would have it than only the Sulphur of the Mixt retained in a portion of water under the
also it is That fat persons are the smallest Eaters by reason of the lack of internal Heat But a little after the Doctor speaks yet more fully to the Purpose Qui sanguinem habent sale volatilizato bene suturatum ●i sunt minus Febribus obnoxii hinc etiam qui saepius sanguinem emittunt ad Febres aptiore sunt Thus far he whose single Testimony in sufficient And since it appears That it doth so little hinder the approach of a Feaver that it rather furthers it it seems impossible That it should absolutely and alone cure any Fever For it is granted by all Physicians That a Fever has a property to pollute the Blood and that this can be taken away à posteriori that is by withdrawing what is putrified and contaminated seems very absurd to think being contrary to that Philosophick Axiom Manente causa manet Effectus Besides It is generally believed That the material cause of a Fever do's not possess the Vessels about the heart but rather the Vena cava and therefore how can Blood-letting be supposed to remove either the efficient or material causes thereof Wherefore consequently it can be no true Remover of a Fever but only an Abater of one of its most troublesem Symptoms viz. Heat which it do's by impoverishing the Stock of vital Spirits which maitaining Contest with the Radix of the Fever does by that contentious Motion cause that preternatural excessive Heat and Ebulition of the Blood which is particularly affected therewith hence it is That old Persons whose vital Spirits are poor in quantity and consequently not able to combate so strongly with the Disease do not appear so hot in a Fever as those whose Spirits are stronger and in a larger quantity and other persons after a tedious Warfare with this cruel Disease some small time before Death the Spirits having given up the Victory as not being able any longer to oppose the same do seem to be totally freed from all the Symptoms of their Fever For as I said the Spirits by reason of their Paucity and Imbecility do then resign up their noble Members to the Mercy of the Disease whose truculent Forces quickly invades the very Royal Pavillion of Life it self and as suddenly subverts it by committing it into the frozen Arms of a drowzy Death Whence it is held as a dangerous Prognostick when a Fever abates in the Violency of its Symptoms without any CRISIS or natural Assistance or without any medicinal Aid or without any certain Signs of approaching Health as well as sure Tokens of Nature's obtaining the Victory over the Disease So that it is no Wonder why Phlebotomy seems to afford so great Refreshment to the afflicted even in the most troublesom Symptoms because by depriving Nature of some of her provoked Forces it compells the rest for want of Power to suffer patiently the Cruelty of the Disease which if it be not very malignant as those Fevers called Ephemera Synochus non putrida and sometimes in those putrid ones called Synochus putrida and the continual Quotidian Tertian and Quartan the Contention ceasing and the corrupted blood being partly let out and the rest by some proper Medicament being corrected and amended Nature doth with much Difficulty and with great Debility at length obtain a pleasing Health Now if Phlebotomy did only let out the corrupted Blood and left still behind those Spirits which used to flow with it then Blood-letting by partly removing the Effect might ease Nature of a great deal of that which she otherwise must with abundance more Toil cast out And Reason would tell us That the natural Forces being still the same in Quantity and Power and the Inimical vitiated Blood being diminished and partly let out Nature must needs be the better able to cast out and purge the rest But since we find that the Blood and Spirits are Correlatives and do issue out together the Spirits going forth in such Quantity and the Blood let forth could be Vehicle too This proves then That Phlebotomy as it doth take away some of the corrupted Blood so it takes away also those Spirits which might have assisted to its correction some better way thereby rather weakning than assisting Nature But Phlebotomy being used in any malignant Disease is utterly destructive without a Miracle for in the Meazles Small Pox Plague c. It most commonly obstructs Nature in her Intentions so much debilitating her strength that she oft proves unable to cast forth the malignant Matter but by its poison is wholly over-come and destroy'd or at least is not capable of making an exact Purgation and though with extream hazard she escape Death yet there is such a stock of malignant matter left behind secretly lurking in the Mass of Blood which will upon a small Excitation discover its presence there by untoward troublesom Symptoms unless by powerful Remedies it be dispossest before it has fermented it self to that height It has been the Audacity of some Physicians to prescribe Blood-letting even in the Small Pox and Plague supposing That in the first the corrupted Blood being partly let out it would be impossible that the afflicted persons should have so many of those deforming Pussles as they otherwise would have had and therefore Blood-letting in such Cases might be lawful if it were upon no other account but the preserving the threatned Beauty of a youthful Face 'T is true by allaying the Effervescence of the Blood and weakning the expulsive Faculty partly as they say by reason part of that Corruption is let forth which otherwise perhaps might have made some hundreds of those filthy Pussles There is if the Diseased escape Death a great diminution of them and thereby those sweet Features which they before possest are not wholy rased But that this cannot be performed without ●●nifest Hazard of the Patient's Life Experience and Reason hath shewen since so many great Persons have fell meerly to save a handsome Face The Spirits by Blood-letting being diminished and enervated so that they can no longer endeavour for their own Recovery for as Hippocrates saith Natura est morborum Medi●a●ri● Besides Phlebotomy generally by weakning the retentive Faculty produces a Diarrhaea which was ever accounted a dangerous Symptom in malig●●● Diseases but most particularly in the Small Pox and upon this Account it is That Phlebotomy sometimes by producing 〈◊〉 accident on the a simple Feaver But in the Plague they pretend That the opening of a Vein is necessary for Prevention sake Be●ause the less Effervescence is in the Circulation of the Blood the less obnoxious we are to the Contagion The most noted man of this Opinion I find to be the above mentioned Dr. Willis in his Book of Fevers pag. 157. Where he saies Vbi adest Plethora cum magna sanguinis Turgescentia ●ut quibus longa Consuetudine sanguis solenniter mitti solebat iis venam secare convenit quo enim sanguis minus effervescet sine tumultu in
the Composition of Lac Virginis The Smell is an affection of the olfactory Nerves and the Tast is also one of the papillous Nerves of the Tongue as colours are of the Retain There is so great a Relation between the Taste and Smell that those things which are agreeable to the Smell are also almost alwayes to the Taste Whence it comes That the most part of Animals smell their Aliments before they tast them and they do not eat them except they find them agreeable to their Smell as we may take notice of it in Apes All the Difference between these two Senses is That the Particles which cause us to Smell are a great deal more subtile and thin than those which cause us to Taste As there are no Colors which we do not behold but by the different mixtures of Acids with Alkali's so there is also no Savour nor Odors which we do not perceive according to the divers Mixture of these two Salts 1. EXPERIMENT Which proves that Odours come from Acid and Alkali OIl of Roses drawn by Distillation which is an envelloped Acid mixt with a sufficient great quantity of water hath almost no odour but mingled with Salt of Tartar which is a powerful Alkali it makes a fluid Composition some drops of which being mingled with a quantity of water makes the water one of the most delectable odours in the World. 2. EXPERIMENT Which proves the same SUlphurs of Minerals which are envellopod Acids being to be dissolved by Fire or some other Dissolvant cast forth an odour as stinking as that of the Oil of Roses drawn by Distillation but mixt with some Alkali it 's pleasant 3. EXPERIMENT Which proves that the Difference of Tasts comes from the Diversity of Acids and Alkali's EXperience shews us That Saltness comes from the Mixture of Acids with Alkali's Soap which is salt gives us a familiar example thereof It is made with pure Alkali's and Oil which is an enveloped Acid. 4. EXPERIMENT Which proves that the Diversity of Savours depends upon the different Mixture and particular nature of Acids 〈◊〉 Alkali's SIlver reduced into Cristals by spirit of Niter which is a powerful Acid become of an extream bitter Tast Lead on the contrary dissolved in distilled Vinegar and reduced into salt acquires the sweetness of sugar c. I could bring several other Experiments to prove that the diversity of Odors and Savours depends upon the different Mixture of Acid and Alkali But tho' I have discoursed you thereof elsewhere I shall yet bring you one more sufficiently familiar which is that of Wine Wine having another Tast and another Smell before it is fermented than it has when it is fermenting or after it is Fermented for it changes by little and little its green Taste into a plesanter and becomes at last sour and loseth its temperament of Wine and all these changes happens to it according 〈◊〉 the Acids and Alkalies which are found therein are more or less intangled and 〈◊〉 as one of them is more or less exalted and there is almost no odor or savor through which it doth not pass before it grows four There remains no more but that I speak two words of the passive Principles The Water is the first of these Principles it serves as I have already told you as a Vehicle to the Acid and Alkali salts it serves also to dissolve them and put them in Motion because Salts act not except they are dissolved Salia non agunt nisi dissoluta Water causes the Destruction of Mixts when it is found therein in too great a quantity as it compacts them and strictly unites their parts when it is found therein in a lesser quantity and it fills up the empty spaces which it meets with therein The Earth or Caput Mort. on the contrary being extreamly porous and light makes a great many vacancies in Bodies wherein it is found but on the other hand it hinders that those bodies be not destroy'd by the abundance of flegm It is unnecessary to bring you a great many Experiments to prove that Water and Earth are found in all Bodies and That they are Principles thereto but without any action I believe you are sufficiently convinced thereof and have several times observ'd That there is no Body from which we cannot draw some Flegm by Distillation and which leave not some Earth after Calcination and though we work never so much on Water and Earth it is Impossi to draw any other thing therefrom but water and Earth You are not ignorant also That rotten wood which hath no Acid and Alkali Salts and which hath nothing but some Flegm and Earth hath no more any action PYR. I could wish you would a little longer explain what you mean by the words Fermentation and Precipitation whereof you make use so often EUBUL By the Word Fermentation I mean an Internal Motion of all the parts of Bodies which are fermented in such Manner that they take no more the same place nor scituation as they had before and that they change consequently or at least alter very much the nature of the bodies which are fermented as for the difference of Effervescence in which there is made only a simple Motion of the integral parts of Mixts by the force of some exteriour Agent as Fire the which parts re-take afterwards the same scituation which thy occupied before unless their natures and qualities be in any wise changed There are several sorts of fermentations in Nature some are made with Effervescence as that which happens upon the mixture of Oil of Vitriol with Oil of Tartar and others are made without Effervescence as it happens in an Eg which a Hen hatcheth and in common Water when one casts thereinto some Drops of well-deflegm'd Spirit of Vitriol and this Fermentation is known only by the Heat which we feel at that instant There are some which are made without Heat as that which is made of Vitriol dissolved in water with Oil of Tartar There are some which are made with Fires and Flames as the Fermentation which is made of Calx Vive in the time it is sprinkled with a little Vinegar and others which are without Fire or flame as are the ordinary Fermentations There are still some sensible and insensible sensible as the Fermentation of Spirit of Niter with Oil of Tartar and insensible as that of Wine which sours PYR. Whence comes it that there are so many sorts of Fermentations EUB. Either Bodies are fermented of themselves as Wine or they are fermented by means of a Ferment as Dough with Leven either the Acid Salts and Alkali Salts are Exalted or else they are Intangled one in the other and in the Passive principles one of them is exalted and the other Intangled or one of them is in a great quantity and the other in a small quantity If the Acid Salts and Alkali Salts are each as powerful as the other the Fermentation cannot be made without Heat and
produce this Effect Acids assisting to make this Coagulation as Country-women observe Therefore consequently there may be Alkali in Iron We see likewise by another familiar Experiment That there is Acid in Iron for if one puts a bit of iron into Sauce wherein there is some Gall as in that of a Carp the Gall of which one has broke all the Volatile Alkali which causes the bitterness of the Gall joins it self to the Iron and the Sauce remains sweet How should this be that this Volatile Alkali doth join it self to the Iron if there was not Acid in the Iron seeing Alkali cannot produce such an Effect it follows therefore That there is Acid in Iron PYR. He afterwards demands the Reason Why Mercury which dissolves Gold so readily it being a hard and solid Body and reduces it into an Amalgama acts not at all upon filings of Iron though this is a Metal so open that Liquors weak enough work upon it EUB. Two things contribute to this Effect The first is That there is a great deal more Sulphur in Gold than in Iron and consequently Mercury which abounds in Alkali can rather work on Gold than on Iron The second is That the Sulphur of Iron is intangled in a great quantity of Earth which hinders the Action of the Mercury which has not parts sufficiently subtile nor sufficiently penetrating to dis-intantangle it as the Spirits of Niter and sal Armoniack do whose parts are so thin and so agitated that they dis-intangle the parts of the Iron one from the other and makes a Dis-union of its Sulphur and Alkali it is not so of Gold whose Sulphur is only intangled in its Mercury and which hath only a very little Earth which is not strong enough to intangle the parts of the Sulphur and Mercury of Gold. PYR. The same thing happens which he pursues to the same End In the Precipitation which is made of Corals and Peals dissolved in distilled Vinegar with Oil of Tartar made per deliquium Chymists attribute this Precipitation to the Alkali of Tartar which absorbs the Acid spirits of the Dissolvant and nevertheless we see That Acids precipitate them as well as Alkali's EUB. I do not wonder That Acids precipitate equally with Alkali's Corals and Pearls dissolved in distilled Vinegar Yet that does not at all destroy the Reason That they are wont to render when it is made with Alkali's for there are as you know Two sorts of Dissolutions in Nature either an Acid dissolves an Alkali or else an Alkali dissolves an Acid if it is an Alkali which holds an Acid in Dissolution the Precipitation cannot be made but by an Acid for then the Alkali which held it in Dissolution quits it to join it self to the new Acid that is cast thereto If on the contrary 't is an Acid which holds an Alkali in Dissolution either the Alkali dissolved by this Acid is mixed intimately with its dissolvant in such manner that the dissolvant fills exactly all the pores of the dissolved body as it happens in Vitriol of Mars or the dissolvant do's not penetrate the Body but superficially and do's not throughly fill the pores thereof as we observe in Mercury dissolv'd in Aqua fort and in Coral and Pearls dissolved in distilled Vinegar If it happens that the Acid spirit penetrates intimately the Boto which it is joined and that those points be of the same figure and grossness as the Pores of that Body the Precipitation cannot be made but by an Alkali which charges it self with the Acid which held that Body in dissolution and makes it at that instant to quit its hold The which Acids cannot do because that not finding therein any Vacuity they cannot work upon it If the Dissolvant is not mingled per minima with the dissolved Bodys an their points are not of a figure proportionated to those of the pores of the Body the Precipitation thereof may be made by Acids and Alkali's by Alkali's after the same manner as I told you but now and by Acids because the points of these Acids work upon those of the Dissolvant causing them to quit their hold for the Body being no longer agitated nor detained by those points it falls by its own weight to the bottom of the Vessel which contains it Thus when Oil of Tartar precipitates Corals and Pearls dissolved in distilled Vinegar they have Reason to say that this Precipitation is done Because the Alkali of Tartar has blunted and charged it self with the points of the distilled Vinegar which held the Coral and Pearls in Dissolution altho Acids precipitate also this Dissolution PYR. Our Author saith Chapter the Third That the Admirers of Acid and Alkali seem to have assign'd arbitrarily certain Extents and Employments to each of these Principles as for Example That an Acid doth in quality of an Acid such and such Operations and the Alkali's in their quality the like also and That from thence depends all the Phaenomena's of Nature and That they ought not to promote in publishing Propositions of this Importance without good and sufficient Proofs thereof EUB. Does not Experience teach us That Acids of whatsoev●r Nature they be coagulate Blood Milk c. That they ferment with all Alkali's and never with other Acids That they constitute the Essence of all Bodies that they are the pointed Bodies which fills up the Vacuities of Alkali's and which are the absolute Masters thereof That Alkali's on the contrary dissolve Blood and Milk coagulated by Acids That they hinder them also from being coagulated and that their parts are not dis-united one from the other For Example sake If one mingle som volatile Spirit of Sal Armoniack with new Milk or with Blood so soon as it comes out of the Vein it conserves them in their Consistence for a great while and hinders them from being corrupted Alkali's whiten Linnen and Stuffs they ferment well all Acids and never with other Alkali's These are the little Bodies full of holes and wholly vacuous in a word They precipitate Vitriol of Mars dissolv'd in Water which Salts nor Acids can never precipitate You thus see plainly That they assign not in vain these nor several other Effects to Acid's and Alkali's seeing Experience teacheth you That they are alwaies and at all times the Cause thereof PYR. He affirms also That the Division of Salts into Acid and Alkali is purely arbitrary and That they may divide them otherwise Acids and Alkali's having not only in a great many things some agreement but also salts of one and the same Denomination being visibly different in several chief points as Alkali's whereof some are fixed others volatile and some thereof give a Precipitation of corrosive Sublimate dissolved in water of a tawny colour as salt of Tartar others a white colour as spirit of Urine Harts-horn c. Finally some act very slowly on filings of Copper as Oil of Tartar made per deliquium and others dissolve it with readiness as spirit
of Urine c. he adds also That there is no less Difference between Acids some dissolve Bodies which others cannot dissolve as Aqua Fortis which dissolves Silver Mercury c. and touches not Gold and as Aqua Regis which dissolves Gold and touches neither Silver nor the other Metals Spirit of Vinegar well deflegm'd dissolves Lead in the Cold and reduces it into minute parts which Spirit of common Salt cannot do and he concludes this Chap demanding whether Acid and Alkali have the Simplicity that a Philosopher requires in Principles and in Smiling at the Definition that they are Wont to give That Acid is an Enemy to Alkali and Alkali to Acid. EUB. The Division of simple Salts into Acid and Alkali is as Just and Exact as can be wish'd Acids and Alkali's having not any agreement in Virtue and Property and the one never produceth the Effects of the other as Mr. Boyle would have it as for Example Alkali's are Bodies vacuous and full of holes which precipitate Vitriol of Mars dissolved in Water which whiten Linnen and Stuffs which make a Dissolution of Milk and Blood coagalated by Acids c. Acids on the contrary are pointed Bodys which fill up the little holes they meet with in Alkali's which foul Linnen and Stuffs which coagulate Blood and Milk c. in a word which have not any of the Properties of Alkali's And though Salts of one and the same Denomination differ in some things yet nevertheless they all agree in Nature and use for we see That Alkali's whether fixed or volatile are Bodys full of holes That they all precipitate Vitriol of Mars That Acids on the contrary are pointed Bodies c. so that when some Alkali's precipitate corrosive Sublimate dissolved in water into a tawny coloured Powder and some others into a white powder that does not prove That they have a different Nature one from the other but that comes from the Diversity of their Pores some having them more conformable to the Acid which had sublimed the Mercury and others less and they blunt after this manner more or less the points of those Acids whence comes the Diversity of colours of the precipitate It is not also the Diversity of Natures that makes that Volatile Alkali's dissolves Copper more readily than fixed Alkali's do but only the greater agitation of their parts all Acids work on Silver and the other Metals but more or less according to the greater or lesser Relation their points have with the pores of those Metals These Acids never work on Gold which cannot be dissolved but by salt Menstruums as I have said else-where And whatsoever Mr. Boyle says of spirit of Salt which he cites for a most powerful Acid is Salt and not a pure Acid notwithstanding the Acid seems to predominate therein and That is the Reason why spirit of Salt works neither on silver nor the other Metals These two Salts have the Simplicity that a Philosopher requires in Principles because they are composed of Particles of one and the same Nature and can never be resolv'd into any other Substances In respect of the Definition which Mr. Boyle relates of Acid and Alkali he has Reason to blame it because he doth in no wise explain the Nature of these Principles no more than if one should say That that which dissolves a Body dissolvable by an Acid ought to be an Acid That all which precipitates a body dissolv'd by an Acid ought to be an Alkali but Mr. Boyle cannot say the same thing of the Definition which I have already so many times repeated concerning Acid and Alkali That the Acid is a Salt composed of small pointed parts which ferment with Alkali's makes the Essence of all Bodies The Alkali on the contrary is a vacuous Salt which ferments with Acids and precipitates Vitriol of Mars dissolved in water This Definition explains clearly their Nature Kind and Difference for these two Principles agree in that they are Salts and they differ in that one of them is pointed and the other porous and unequal and that one fills the Pores of the other and is its absolute Master PYR. This Famous English-Man will not allow Chap. 4. That the Fermentation or Heat and Ebulition which is caused when these Two Salts are mingled together is a sure Token to know Acid and Alkali For he pretends That these Effects depend principally on the Mechanick Disposition and Construction of Parts and That 't is sufficient to produce heat when the parts of a Body are agitated with vehemence on all sides and for the Ebulition That the Bodies which are mingled intercept the parts of the air or the warm Vapours in the time that they are excited and That there happens often in this mixture Heat without Ebulition and Ebulition without Heat He relates some Experiments of both For he saith When Oil of Vitriol which is a powerful Acid or Salt of Tartar which is a powerful Alkali are mingled with Water which is neither Acid nor Alkali There is at that time a considerable heat excited without any Ebulition and That on the contrary in the Mixture which is made of spirit of verdigriss made per se which is an Acid with salt of Tartar there is made a great Ebulition and gross Froth without any remarkable heat EUB. It is very true That the Heat and Ebulition which happens in Fermentation depends upon the Mechanick disposition and Construction of the parts of Bodys which are Fermented But this Construction or Disposition likewise depends wholly upon the different nature of Acids and Alkali's and their divers mixtures one with the other as I have already caused you to observe where I spoke of Fermentation and its Differences which would be needless here to repeat as for the oil of Vitriol and Salt of Tartar which heat water when they are dissolved therein you shall observe That there is in Oil of vitriol a metallick part of Iron or Copper according to the Nature of the Vitriol which was elevated in the Distillation by the Acid of that Salt as Experience sufficiently teacheth us This oil coming to be dissolved in the water there is then made a separation of the Metallick part from the Acid which had elevated it and an action of that Acid upon the Alkali of the water which is powerful enough since it hardens red hot Iron and hinders it from going into scoria's when it is squenched therein for there is none but Alkali's which can produce this effect then there is made on all sides an agitation of their parts with sufficient Vehemence whence comes the heat which happens in this mixture In regard of that which results from the mixture of salt of Tartar with water you shall understand that salt of Tartar does hot heat water but when it is too much or too little calcined when it is too much calcined it is charged with an Acid from the fire which coming to be dissolved in water it separates
it self from the Alkali of the Tartar and acts upon that of the water and causes as I have said but now the heat in the water and when the Tartar is not sufficiently calcined it retains some of its own Acid and becomes a little near the nature of Calx vive which causes it to ferment in water but when this Salt is neither too much nor too little calcined it dissolves simply in water without causing therein any Heat as all pure Alkali's do PYR. He afterwards comes to speak of the Tast which he saies is as the Touch-stone to know Acids and Alkali's he saith thereupon That there are a great many mixts in which the Tast can so little discern which of those two Principles predominate therein that one cannot suspect that there is in those two Bodys the least part of those Two Salts as in Diamons Rubys Gold Silver c. That there are also several Bodys which abound in Acid and Alkali Salts yet have no tast at all or which have one altogether different from that which the Chymists attribute to their Principles as Venice Glass which is insipid on the Tongue though it is almost no other thing but fixt Alkali and as Cristals of Silver and Lead made with aqua fortis whereof the first has an extream Bitterness and the last the sweetness of Sugar neither of which retain any thing of Acid of the aq Fort. which did dissolve those Metals EUB. By the Taste we can only know pure Acids and Alkalis as the Spirits of Sulphur Niter c. which are taken Notice of by their acidity and as the volatile Alkali's of Viper Harts-horn and fixed Alkali's as lixivial Salts which are known by their great acrimony as soon as these two Salts are mixt together they produce different Savours according to the divers Mixture and particular figure of their Parts It happens also very often that a body which experience teacheth us a acid being mingled with a Body which experience makes us know to be an Alkali they being insipid as for Example When four parts of Cream of Tartar dissolved in Water in which may be manifestly seen that the Acid predominates is mingled with two parts of Salt of Tartar dissolved also in water there is made as soon as they come together a Fermentation sufficiently violent from which afterwards is obtained by Cristallization a salt which is altogether insipid You see by this Experiment That though a Body be insipid nevertheless one may not conclude That it c●ntains neither Acid nor Alk●li● therein PYR. Mr. Boyle pretends is the fifth Chapter That the Hypothesis of Acid and Alkali is neither Necessary nor Useful to explain that which happens to qualitys Whereof some are produced others destroy'd or altered it not appearing Th●t these two Principles contributed in any wise thereto as when Water is changed by the force of Beating into Froth which hath some Consistence or as when Coral which is red and transparent is changed into a white and opacous Powder without doing any other thing thereto than reducing it into a Powder sufficiently subtil to pass through a fine Searce EUB. The Froth which is formed on water by Beating comes only from the agitation of its parts and as there are a great many Alkali parts and also some Acid parts and a little Earth to be met with in water it is certain That these Principles contribute to the Production of this Quality It should be needful that Mr Boyle prove That there is no Acid nor Alkali in water to conclude That Acid and Alkali do not contribute in any wise to the production of this new Quality which is impossible to be done as for the Coral which becomes white and opacous when it is reduced into an Impalpable Powder I shall tell you That the most part of Bodies are destroy'd by Trituration and entirely change their Nature and those also which are harder and solider and if we may believe some of the Renouned Chymists of our Age as the famous Langelot Olaus Borrychius Schroder c. Leaf-Gold is destroyed in such wise by a long Trituration that it is impossible to make it retake the form of Gold whatsoever artifice you use so that it is not strange That Coral which is red and transparent should become white and opacous when it is reduced to an impalpable powder because that in the Trituration which is made thereof its parts are dis-united in such wise one from the other and are in so great a confusion that they can no longer keep their natural colour either because they do no longer reflect the light as they did reflect it before or because they do not make the same Impression on the aier or lastly that the Attoms which go out therefrom are not conditioned as they were and this colour cannot return to it except by the force of some exteriour agent its particles retake the same place and the same scituation as they occupied before the Trituration as we take notice of it in blew Vitriol which becomes white when reduced into pouder and which retakes its natural colour when this powder is dissolved in water and afterwards caused to cristallize PYR. He proceeds with an Objection like the former He saies They cannot render a Reason by Acid and Alkali of Gravity Light and several other Qualities which are called MANIFEST and much less of those which are called OCCULT as of the Force of the Loadstone on Iron and of Iron on the Loadstone as well as several other Phaenomena's of the Loadstone EUB. The gravity and levity of a body depends upon the more or less of Vacuity that there is in that body according to Mr. Boyle's Opinion in such manner That a body in which there are fewest Vacuities is most Weight as on the contrary that in which there are more vacuitys is more light Now the Moreness or Lessness of Vacuities depends upon the Moreness or Lessness of the acid which there is in Bodies for when there is a great deal of Acid therein the Pores of the Alkali are filled therewith and when on the contrary there is but a very little Acid those Pores remain empty and consequently the gravity of a Body depends upon the quantity of Acid that is found therein and the Levity upon the smallness of the Acid and quantity of Alkali which is found therein The abundance of Caput Mort. contributes much to the lightness of Bodys as we observe in the Firr-tree which is a very light wood and hath much Earth in it Light is no other but an agitation of small pointed Bodys which are poured out in the air and puts all the parts thereof in Motion It is of the same Nature with fire since it produceth the same Effects and that being re-united in a burning-glass it liquefies Metals and calcines Stones as fire doth which is Acid as I have proved else-where and by consequence Light ought also to be an Acid since it hath all the
least Harm yea be very Beneficial by accident in some Respects in some few Diseases of which the most noted are a Frenzy Quinsy Pleurisy an inveterate and stubborn Head-ach and in some Fevers which be in no wise malignant as also in Contusions Rheumatisms and Intermitting Fevers but it must be in young and strong Bodies if it be done without any cause of Fear and in some few other Diseases But especially it is most proper to temper the plethorick Bodies of our age who by an extravigant Destruction of vious Liquors cause themselves to abound in that pretious balsamick vital Liquor It helps a Frenzy by abating the Effervescence of the Blood in diminishing the Vital Spirits It helps a Quinzy by Revulsion and drawing back the Blood into the Veins which would have putrified there that it may supply the loss of that which was let out In a Pleurisy it obstructs also the Apostumation of the Blood collected in the Pleura and Intercostal Branches of the Aorta by Revulsion for that Blood there ready to putrify by reason of the great heat of the Parts and its own Disposition to Putrefaction does as the Blood is drawn out of the Arm repass into the Superiour Arteries and so becomes again circulated in them the Abscess thereof being thereby prevented It cures an inveterate Head-Ach by reason it appeases the Fury of the Spirits there and by reason it depleats the Veins and Arteries wherefore 't is they are not so distended and pained as before And as for Fevers I have told you already how it comes to be assisting to their Cure only intermitting Feavers accidentally are cur'd by altering the Cirlation and by putting Nature into a Fear of Death wherefore she musters up all her Forces to oppose it whereby very often the Root of the Fever is in this great Hurry and Commotion cut off and expell●● for as Duretius saith Animi act ones incidente aliqua occasione fortius agunt presertim in morturis Whence also in Swoonings and Aopoplectick fits it proves beneficial and hence also it is That great Fears have often been a means by stirring up all the natural Forces for their own Safety to rid some Persons of chronick accute and almost incurable Diseases as Experience has often manifested Rheumatisms it cures by Derivation and so it doth som Coughs by causing the sharp Lympha which Tickles the Lungs by its sharp pointed Corpuscles the which also afflict the Nerves and Tendons with accute Pains to be discharg'd from thence mediately into the subclavian Veins to supply the loss of the Blood let out and into the Mesenterial Glandula's to be mixed with the Chyle also to promote the speedy making the like quantity of Blood hence sometimes doth the Cause of a greedy Appetite proceed afte● Blood-letting and after the retreat of a sharp Disease for Nature being studious to repair her loss and especially When she has not been too much weakned by the Disease or Blood-letting do's manifest her wants by these hungry Symptoms It seems to assist the Circulation of the Blood when it is congealed by reason of the Obstruction of its Circulation in the small Veins which by the Contusion are so squeezed that they wholly deny its flux because it seems to afford it more Room for that Circulation but if we consider That the Blood is Conglebated only as I said in the smallest Veins and that the thinnest and most fluid Blood spins out at the Orifice we cannot think it can much further its quiet Circulation since fluidity is the greatest Promoter of it Lastly By its wasting the Spirits and depriving us of that pure nutritive Juice the Blood it keeps us back not suffering Nature to store up so much Nutriment to her self and thereby renders us equally as needy as if we put a greater restraint upon our Appetites and indulged them far less than we do To the former Advantages by Phlebotomy here is added by another hand this further Benefit viz. That it is of excellent use for Women whe● their Terms dodg with them and begin to leave them and to prevent the settling of them in their Limbs or in their own Vessels putrifying and causing Ulcers Sores Piles and Fistula's in the inferiour Parts c. to prevent all which Evils Women so affected ought to bleed once a month for 3 Months together FINIS Errores Phlebot p. 10. l. 18 Crebrò p. 11. l. 5. Fat. p. 12. l. 6. above p. 15. l. 5. as the. Advertisement All Dr. Salmon's Works are certainly to be sold by Tho. Dawks living on Addle hill in Carter-lane near S. Paul's Church-yard Also the said Doctor 's Medicines truly prepared are in his absence to be sold by his Wife at his House at the Blew Balcony by the Ditch-side near Holborn Bridge There is also preparing for the said Dawks's Press A Practical Discourse concerning Swearing Not only-sharply reprooving the vain false rash inconsiderate Swearer but also chiefly reprimanding the Over-wise Quaker in the midst of all his vain-glorious Shew of seeming Holiness proving that he most abominably abuseth all those Scriptures he brings for Refusing to take an Oath before Authority when the Law of God commands it and the Glory of God as well as the Necessity of his Neighbour require it c. Place this leaf last of all